Coumarins of Loricaria ferruginea

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Synthesis of Functionalized Coumarins

The synthesis of functionalized 2-oxo-2H-coumarin derivatives has been studied by a one-pot reaction of o-hydroxybenzaldehyde, ethyl 2-bromoacetate and triphenylphosphine in the presence of catalytic amount of triethyl amine in EtOAc, water or under solvent free conditions. We have found the best results obtained under solvent free condition.

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Supramolecular photodimerization of coumarins.

Stereoselective photodimerization of coumarin and its derivatives in supra-molecular systems is reviewed. The enantioselective photodimerization of coumarin and thiocoumarin in inclusion crystals with optically active host compounds is also described.

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ژورنال

عنوان ژورنال: Revista Brasileira de Farmacognosia

سال: 2016

ISSN: 0102-695X

DOI: 10.1016/j.bjp.2016.02.006